Radioactive waste

Radioactive waste are waste types containing radioactive chemical elements that do not have a practical purpose. It is sometimes the product of a nuclear process, such as nuclear fission. However, other industries not directly connected to the nuclear industry can produce large quantites of radioactive waste. For instance over the past 20 years it is estimated, that just the oil producing endeavors of the US have accumulated 8 million tons of radioactive wastes.^[1] The majority of radioactive waste is "low-level waste", meaning it has low levels of radioactivity per mass or volume. This type of waste often consists of used protective clothing, which is only slightly contaminated but still dangerous in case of radioactive contamination of a human body through ingestion, inhalation, absorption, or injection.

In the United States alone, the Department of Energy states that there are "millions of gallons of radioactive waste" as well as "thousands of tons of spent nuclear fuel and material" and also "huge quantities of contaminated soil and water".^[2] Despite these copious quantities of waste, the DOE has a goal of cleaning all presently contaminated sites successfully by 2025.^[3] The Fernald site in Ohio for example had "31 million pounds of uranium product", "2.5 billion pounds of waste", "2.75 million cubic yards of contaminated soil and debris", and a "223 acre portion of the underlying Great Miami Aquifer had uranium levels above drinking standards".^[4] The United States currently has at least 108 sites it currently designates as areas that are contaminated and unusable, sometimes many thousands of acres^[5](&DOE)^[6] The DOE wishes to try and clean or mitigate many or all by 2025, however the task can be difficult & it acknowledges that some will never be completely remediated, and just in one of these 108 larger designations, Oak Ridge National Laboratory, there were for example at least "167 known contaminant release sites" in one of the three subdivisions of the 37,000 acre site.^[7] Some of the U.S. sites were smaller in nature, however, and cleanup issues were simpler to address, and the DOE has successfully completed cleanup, or at least closure, of several sites.^[8]

The issue of disposal methods for nuclear waste was one of the most pressing current problems the valuable international nuclear industry faced when trying to establish a long term energy production plan, yet there was hope it could be safely solved. In the U.S., the DOE acknowledged much progress in addressing the waste problems of this vital and critical industry, and successful remediation of some contaminated sites, yet also major uncertainties & sometimes complications and setbacks in handling the issue properly, cost effectively, and in the projected time frame.^[9] In other countries with lower ability or will to maintain environmental integrity the issue would be more problematic.

Sources of waste

NORM (naturally occurring radioactive material)

Processing of substances containing natural radioactivity, this is often known as NORM. Much of this waste is alpha particles emitting matter from the decay chains of uranium and thorium. The main source of radiation in the human body is potassium, K-40.

Coal

Coal contains a small amount of radioactive nuclides, such as uranium and thorium, but it is less than the average concentration of those elements in the Earth's crust^{[citation needed]}. They become more concentrated in the fly ash because they do not burn well [1]. However, the radioactivity of fly ash is still very low. It is about the same as black shale and is less than phosphate rocks, but is more of a concern because a small amount of the fly ash ends up in the atmosphere where it can be inhaled.[2].

Oil and gas

Residues from the oil and gas industry often contain radium and its daughters. The sulphate scale from an oil well can be very radium rich, while the water, oil and gas from a well often contains radon. The radon decays to form solid radioisotopes which form coatings on the inside of pipework. In an oil processing plant the area of the plant where propane is processed is often one of the more contaminated areas of the plant as radon has a similar boiling point as propane.^[10]

Mineral processing

Wastes from mineral processing can contain natural radioactivity, the largest source of this are phosphate mining operations.

Medical

Radioactive medical waste tends to contain beta particle and gamma ray emitters. It can be divided into two main classes. In diagnostic nuclear medicine a number of short-lived gamma emitters such as technetium-99m are used. Many of these can be disposed of by leaving it to decay for a short time before disposal as normal trash. Other isotopes used in medicine, with half-lives in parentheses:

• Y-90 , used for treating lymphoma (2.7 days)
• I-131 , used for thyroid function tests and for treating thyroid cancer (8.0 days)
• Sr-89, used for treating bone cancer, intravenous injection (52 days)
• Ir-192 , used for brachytherapy (74 days)
• Co-60, used for brachytherapy and external radiotherapy (5.3 years)
• Cs-137, used for brachytherapy, external radiotherapy (30 years)

Industrial

Industrial source waste can contain alpha, beta, neutron or gamma emitters. Gamma emitters are used in radiography while neutron emitting sources are used in a range of applications, such as oil well logging.[3]

Nuclear fuel cycle

Main articles: Nuclear fuel cycle and Spent nuclear fuel

Front end

Waste from the front end of the nuclear fuel cycle is usually alpha emitting waste from the extraction of uranium. It often contains radium and its decay products.

Uranium dioxide (UO₂) concentrate from mining is not very radioactive - only a thousand or so times as radioactive as the granite used in buildings. It is refined from yellowcake (U₃O₈), then converted to uranium hexafluoride gas (UF₆). As a gas, it undergoes enrichment to increase the U-235 content from 0.7% to about 4.4% (LEU). It is then turned into a hard ceramic oxide (UO₂) for assembly as reactor fuel elements.

The main by-product of enrichment is depleted uranium (DU), principally the U-238 isotope, with a U-235 content of ~0.3%. It is stored, either as UF₆ or as U₃O₈. Some is used in applications where its extremely high density makes it valuable, such as the keels of yachts, and anti-tank shells. It is also used (with recycled plutonium) for making mixed oxide fuel (MOX) and to dilute highly enriched uranium from weapons stockpiles which is now being redirected to become reactor fuel. This dilution, also called downblending, means that any nation or group that acquired the finished fuel would have to repeat the (very expensive and complex) enrichment process before assembling a weapon.

Back end

The back end of the nuclear fuel cycle, mostly spent fuel rods, often contains fission products that emit beta and gamma radiation, and may contain actinides that emit alpha particles, such as uranium-234, neptunium-237, plutonium-238 and americium-241, and even sometimes some neutron emitters such as californium (Cf). These isotopes are formed in nuclear reactors.

It is important to distinguish the processing of uranium to make fuel from the reprocessing of used fuel. Used fuel contains the highly radioactive products of fission (see high level waste below). Many of these are neutron absorbers called neutron poisons in this context. These eventually build up to a level where they absorb so many neutrons that the chain reaction stops, even with the control rods completely removed. At that point the fuel has to be replaced in the reactor with fresh fuel, even though there is still a substantial quantity of uranium-235 and plutonium present. Currently, in the U.S., this used fuel is stored. In other countries, such as the United Kingdom, France, and Japan, the fuel is reprocessed to remove the fission products, and the fuel can then be re-used. This reprocessing involves handling highly radioactive materials, and the fission products removed from the fuel are a concentrated form of High Level Waste as are the chemicals used in the process.

Proliferation concerns

Main article: nuclear proliferation

When dealing with uranium and plutonium, the possibility that they may be used to build nuclear weapons is often a concern. Active nuclear reactors and nuclear weapons stockpiles are very carefully safeguarded and controlled. However, high-level waste from nuclear reactors may contain plutonium. Ordinarily, this plutonium is reactor-grade plutonium, containing a mixture of plutonium-239 (highly suitable for building nuclear weapons) and plutonium-240 (an undesirable contaminant and highly radioactive); the two isotopes are difficult to separate. Moreover, high-level waste is full of highly radioactive fission products. However, most fission products are relatively short-lived. This is a concern since if the waste is stored, perhaps in deep geological storage, over many years the fission products decay, decreasing the radioactivity of the waste and making the plutonium easier to access. Moreover, the undesirable contaminant Pu-240 decays faster than the Pu-239, and thus the quality of the bomb material increases with time (although its quantity decreases). Thus, some have argued, as time passes, these deep storage areas have the potential to become "plutonium mines", from which material for nuclear weapons can be acquired with relatively little difficulty. Critics of the latter idea point out that the half-life of Pu-240 is 6,560 years and Pu-239 is 24,110 years, and thus the relative enrichment of one isotope to the other with time occurs with a half-life of 9,000 years (that is, it takes 9000 years for the fraction of Pu-240 in a sample of mixed plutonium isotopes, to spontaneously decrease by half-- a typical enrichment needed to turn reactor-grade into weapons-grade Pu). Thus "weapons grade plutonium mines" would be a problem for the very far future (>9,000 years from now), so that there remains a great deal of time for technology to advance to solve this problem, before it becomes acute.

Pu-239 decays to U-235 which is suitable for weapons and which has a very long half life (roughly 10⁹ years). Thus plutonium may decay and leave uranium-235. However, modern reactors are only moderately enriched with U-235 relative to U-238, so the U-238 continues to to serve as denaturation agent for any U-235 produced by plutonium decay.

One solution to this problem is to recycle the plutonium and use it as a fuel e.g. in fast reactors. But the very existence of the nuclear fuel reprocessing plant needed to separate the plutonium from the other elements represents, in the minds of some, a proliferation concern. In pyrometallurgical fast reactors, the waste generated is an actinide compound that cannot be used for nuclear weapons.

Nuclear weapons reprocessing

Waste from nuclear weapons reprocessing (as opposed to production, which requires primary processing from reactor fuel) is unlikely to contain much beta or gamma activity other than tritium and americium. It is more likely to contain alpha emitting actinides such as Pu-239 which is a fissile material used in bombs, plus some material with much higher specific activities, such as Pu-238 or Po.

In the past the neutron trigger for a bomb tended to be beryllium and a high activity alpha emitter such as polonium, an alternative to polonium is Pu-238. For reasons of national security, details of the design of modern bombs are normally not released to the open literature. It is likely however that a D-T fusion reaction in either an electrically driven device or a D-T fusion reaction driven by the chemical explosives would be used to start up a modern device.

Some designs might well contain a RTG using Pu-238 to provide a longlasting source of electrical power for the electronics in the device.

It is likely that the fissile material of an old bomb which is due for refitting will contain decay products of the plutonium isotopes used in it, these are likely to include alpha-emitting Np-236 from Pu-240 impurities, plus some U-235 from decay of the Pu-239; however, due to the relatively long half-life of these Pu isotopes, these wastes from radioactive decay of bomb core material would be very small, and in any case, far less dangerous (even in terms of simple radioactivity) than the Pu-239 itself.

The beta decay of Pu-241 forms Am-241, the in-growth of americium is likely to be a greater problem than the decay of Pu-239 and Pu-240 as the americium is a gamma emitter (increasing external-exposure to workers) and is an alpha emitter which can cause the generation of heat. The plutonium could be separated from the americium by several different processes, these would include pyrochemical processes and aqueous/organic solvent extraction. A truncated PUREX type extraction process would be one possible method of making the separation.

Basic overview

Physics

The radioactivity of all nuclear waste diminishes with time. All radioisotopes contained in the waste have a half-life - the time it takes for any radionuclide to lose half of its radioactivity and eventually all radioactive waste decays into non-radioactive elements. Certain radioactive elements (such as plutonium-239) in “spent” fuel will remain hazardous to humans and other living beings for hundreds of thousands of years. Other radioisotopes will remain hazardous for millions of years. Thus, these wastes must be shielded for centuries and isolated from the living environment for hundreds of millennia [4]. Some elements, such as I-131, have a short half-life (around 8 days in this case) and thus they will cease to be a problem much more quickly than other, longer-lived, decay products but their activity is much greater initially.

The faster a radioisotope decays, the more radioactive it will be. The energy and the type of the ionizing radiation emitted by a pure radioactive substance are important factors in deciding how dangerous it will be. The chemical properties of the radioactive element will determine how mobile the substance is and how likely it is to spread into the environment and contaminate human bodies. This is further complicated by the fact that many radioisotopes do not decay immediately to a stable state but rather to a radioactive decay product leading to decay chains.

Biochemistry

Depending on the decay mode and the biochemistry of an element, the threat due to exposure to a given activity of a radioisotope will differ. For instance I-131 is a short-lived beta and gamma emitter but because it concentrates in the thyroid gland, it is more able to cause injury than TcO₄^- which, being water soluble, is rapidly excreted in urine. In a similar way, the alpha emitting actinides and radium are considered very harmful as they tend to have long biological half-lives and their radiation has a high linear energy transfer value. Because of such differences, the rules determining biological injury differ widely according to the radioisotope, and sometimes also the nature of the chemical compound which contains the radioisotope.

Philosophy

The main objective in managing and disposing of radioactive (or other) waste is to protect people and the environment. This means isolating or diluting the waste so that the rate or concentration of any radionuclides returned to the biosphere is harmless. To achieve this the preferred technology to date has been deep and secure burial for the more dangerous wastes; transmutation, long-term retrievable storage, and removal to space have also been suggested.

The phrase which sums up the area is ' Isolate from man and his environment ' until the waste has decayed such that it no longer poses a threat.

Fiction

In fiction, radioactive waste is often cited as the reason for gaining super-human powers and abilities. An example of this fictional scenario is the 1981 movie "Modern Problems" in which actor Chevy Chase portrays a jealous, harried air traffic controller Max Fiedler; Max Fiedler, recently dumped by his girlfriend, comes into contact with nuclear waste and is granted the power of telekinesis, which he uses to not only win her back, but to gain a little revenge. Another more widely known character affected by a bite from a radioactive spider is Spider-man. The Spider-man character was developed by Marvel Comics (see also Stan Lee) and was portrayed on the big screen by actor Tobey Macguire in two films: the first in 2002, and the second in 2004. In the film franchise, however, it is a bioengineered spider that bites him and changes his genetic makeup.

In most movies and cartoons, radioactive waste in any form is portrayed as steel barrels labeled with the classic radiation hazard symbol, and full of thick, glowing, neon-green liquid. People, animals or objects that have come in contact with radiation or are radioactive themselves are usually shown with a bright green glow around them as well, and sometimes undergo hideous mutations such as the sudden growth of extra body parts, disfigurements, or turning into half-animal hybrids (if a person is bitten by a radioactive animal, much like in werewolf lore). This is often used for comical effect. Most radioactive material in real life however, is neither green nor luminescent (though some have been known to glow in the dark).

In reality, exposure to high levels of radioactive waste may cause serious harm or death. It is interesting to note that the treatment of an adult animal with radiation or some other mutation causing effect, such as a cytotoxic anti-cancer drug, cannot cause that adult animal to become a mutant. It is more likely that a cancer will be induced in the animal. In humans it has been calculated that a 1 sievert dose has a 5% chance of causing cancer and a 1% chance of causing a mutation in a gamete (e.g. egg) or a gamete forming cell such as those in the testis which can be passed to the next generation. If a developing organism such as an unborn child is irradiated, then it is possible to induce a birth defect but it is unlikely that this defect will be in a gamete or a gamete forming cell.

Types of radioactive waste

Although not significantly radioactive, uranium mill tailings are waste. They are byproduct material from the rough processing of uranium-bearing ore. They are sometimes referred to as 11(e)2 wastes, from the section of the U.S. Atomic Energy Act that defines them. Uranium mill tailings typically also contain chemically-hazardous heavy metals such as lead and arsenic. Vast mounds of uranium mill tailings are left at many old mining sites, especially in Colorado, New Mexico, and Utah.

Low level waste (LLW) is generated from hospitals and industry, as well as the nuclear fuel cycle. It comprises paper, rags, tools, clothing, filters, etc., which contain small amounts of mostly short-lived radioactivity. Commonly, LLW waste is designated as such as a precautionary measure if it originated from any region of an 'Active Area', which frequently includes offices with only a remote possibility of being contaminated with radioactive materials. Such LLW waste typically exhibits no higher radioactivity than one would expect from the same material disposed of in a non-active area, such as a normal office block. Some high activity LLW waste requires shielding during handling and transport but most LLW is suitable for shallow land burial. To reduce its volume, it is often compacted or incinerated before disposal. Low level waste is divided into four classes, class A, B, C and GTCC, which means "Greater Than Class C".

Intermediate level waste (ILW) contains higher amounts of radioactivity and in some cases requires shielding. ILW includes resins, chemical sludge and metal reactor fuel cladding, as well as contaminated materials from reactor decommissioning. It may be solidified in concrete or bitumen for disposal. As a general rule, short-lived waste (mainly non-fuel materials from reactors) is buried in shallow repositories, while long-lived waste (from fuel and fuel-reprocessing) is deposited in deep underground facilities. U.S. regulations do not define this category of waste; the term is used in Europe and elsewhere.

High Level Waste (HLW) is produced by nuclear reactors. It contains fission products and transuranic elements generated in the reactor core. It is highly radioactive and often thermally hot. HLW accounts for over 95% of the total radioactivity produced in the process of nuclear electricity generation.

Transuranic waste (TRUW) as defined by U.S. regulations is, without regard to form or origin, waste that is contaminated with alpha-emitting transuranic radionuclides with half-lives greater than 20 years, and concentrations greater than 100 nCi/g (3.7 MBq/kg), excluding High Level Waste. Elements that have an atomic number greater than uranium are called transuranic ("beyond uranium"). Because of their long half-lives, TRUW is disposed more cautiously than either low level or intermediate level waste. In the U.S. it arises mainly from weapons production, and consists of clothing, tools, rags, residues, debris and other items contaminated with small amounts of radioactive elements (mainly plutonium).

Under U.S. law, TRUW is further categorized into "contact-handled" (CH) and "remote-handled" (RH) on the basis of radiation dose measured at the surface of the waste container. CH TRUW has a surface dose rate not greater than 200 mrem per hour (2 mSv/h), whereas RH TRUW has a surface dose rate of 200 mrem per hour (2 mSv/h) or greater. CH TRUW does not have the very high radioactivity of high level waste, nor its high heat generation, but RH TRUW can be highly radioactive, with surface dose rates up to 1000 rem per hour (10 mSv/h). The United States currently permanently disposes of TRUW generated from nuclear power plants and military facilities at the Waste Isolation Pilot Plant.^[11]

Management of medium level waste

It is common for medium active wastes in the nuclear industry to be treated with ion exchange or other means to concentrate the radioactivity into a small volume. The much less radioactive bulk (after treatment) is often then discharged. For instance, it is possible to use a ferric hydroxide floc to remove radioactive metals from aqueous mixtures [5]. After the radioisotopes are absorbed onto the ferric hydroxide, the resulting sludge can be placed in a metal drum before being mixed with cement to form a solid waste form.^[12] In order to get better long-term performance (mechanical stability) from such forms, they may be made from a mixture of fly ash, or blast furnace slag, and portland cement, instead of the normal cement (made with portland cement, gravel and sand).

Management of high level waste

Storage

High-level radioactive waste is stored temporarily in spent fuel pools and in dry cask storage facilities. This allows the shorter-lived isotopes to decay before further handling.

Long-term storage of radioactive waste requires the stabilization of the waste into a form which will not react, nor degrade, for extended periods of time. One way to do this is through vitrification. Currently at Sellafield, the high-level waste (PUREX first cycle raffinate) is mixed with sugar and then calcined. Calcination involves passing the waste through a heated, rotating tube. The purposes of calcination are to evaporate the water from the waste, and de-nitrate the fission products to assist the stability of the glass produced.

The 'calcine' generated is fed continuously into an induction heated furnace with fragmented glass[6]. The resulting glass is a new substance in which the waste products are bonded into the glass matrix when it solidifies. This product, as a molten fluid, is poured into stainless steel cylindrical containers ("cylinders") in a batch process. When cooled, the fluid solidifies ("vitrifies") into the glass. Such glass, after being formed, is very highly resistant to water. [7] According to the ITU, it will require about 1 million years for 10% of such glass to dissolve in water.

After filling a cylinder, a seal is welded onto the cylinder. The cylinder is then washed. After being inspected for external contamination, the steel cylinder is stored, usually in an underground repository. In this form, the waste products are expected to be immobilized for a very long period of time (many thousands of years).

The glass inside a cylinder is usually a black glossy substance. All this work (in the United Kingdom) is done using hot cell systems. The sugar is added to control the ruthenium chemistry and to stop the formation of the volatile RuO_{4 containing radioruthenium. In the west, the glass is normally a borosilicate glass (similar to Pyrex {NB Pyrex is a trade name}), while in the former Soviet bloc it is normal to use a phosphate glass. The amount of fission products in the glass must be limited because some (palladium, the other Pt group metals, and tellurium) tend to form metallic phases which separate from the glass. In Germany a vitrification plant is in use; this is treating the waste from a small demonstration reprocessing plant which has since been closed down.}

In 1997, in the 20 countries which account for most of the world's nuclear power generation, spent fuel storage capacity at the reactors was 148,000 tonnes, with 59% of this utilized. Away-from-reactor storage capacity was 78,000 tonnes, with 44% utilized. With annual additions of about 12,000 tonnes, issues for final disposal are not urgent.

In 1989 and 1992, France commissioned commercial plants to vitrify HLW left over from reprocessing oxide fuel, although there are adequate facilities elsewhere, notably in the United Kingdom and Belgium. The capacity of these western European plants is 2,500 canisters (1000 t) a year, and some have been operating for 18 years.

Synroc

The Australian Synroc (synthetic rock)[8] is a more sophisticated way to immobilize such waste, and this process may eventually come into commercial use for civil wastes (it is currently being developed for U.S. military wastes). The Synroc contains pyrochlore and cryptomelane type minerals. The original form of Synroc (Synroc C) was designed for the liquid high level waste (PUREX raffinate) from a light water reactor. The main minerals in this Synroc are hollandite (BaAl_{2Ti6O16), zirconolite (CaZrTi2O7) and perovskite (CaTiO3). The zirconolite and perovskite are hosts for the actinides. The strontium and barium will be fixed in the perovskite. The caesium will be fixed in the hollandite.}

Synroc was invented by the late Prof Ted Ringwood (a geochemist) at the Australian National University.

Geological disposal

The process of selecting appropriate deep final repositories is now under way in several countries with the first expected to be commissioned some time after 2010. However, many people remain uncomfortable with the immediate stewardship cessation of this management system. In Switzerland, the Grimsel Test Site is an international research facility investigating the open questions in radioactive waste disposal ([9]). Sweden is well advanced with plans for direct disposal of spent fuel, since its Parliament decided that this is acceptably safe, using the KBS-3 technology. In Germany, there is a political discussion about the search for an Endlager (final repository) for radioactive waste, accompanied by loud protests especially in the Gorleben village in the Wendland area, which was seen ideal for the final repository until 1990 because of its location next to the border to the former German Democratic Republic. Gorleben is presently being used to store radioactive waste non-permanently, with a decision on final disposal to be made at some future time. The U.S. has opted for a final repository at Yucca Mountain in Nevada, but this project is widely opposed and is a hotly debated topic, and one of the main concerns is with the long distance transportation of the waste from across the United States to this area, and the possible several accidents over time that would occur. There is also a proposal for an international HLW repository in optimum geology, with Australia or Russia as possible locations, although the proposal for a global repository for Australia has raised fierce domestic political objections.

Sea-based options for disposal of radioactive waste [10] include burial beneath a stable abyssal plain, burial in a subduction zone that would slowly carry the waste downward into the Earth's mantle, and burial beneath a remote natural or human-made island. While these approaches all have merit and would facilitate an international solution to the vexing problem of disposal of radioactive waste, they are currently not being seriously considered because of the legal barrier of the Law of the Sea and because in North America and Europe sea-based burial has become taboo from fear that such a repository could leak and cause widespread damage. Dumping of radioactive waste from ships has reinforced this concern, as has contamination of islands in the Pacific. However, sea-based approaches might come under consideration in the future by individual countries or groups of countries that cannot find other acceptable solutions.

A more feasible approach termed Remix & Return [11] would blend high-level waste with uranium mine and mill tailings down to the level of the original radioactivity of the uranium ore, then replace it in empty uranium mines. This approach has the merits of totally eliminating the problem of high-level waste, of placing the material back where it belongs in the natural order of things, of providing jobs for miners who would double as disposal staff, and of facilitating a cradle-to-grave cycle for all radioactive materials.

Transmutation

There have been proposals for reactors that consume nuclear waste and transmute it to other, less-harmful nuclear waste. In particular, the Integral Fast Reactor was a proposed nuclear reactor with a nuclear fuel cycle that produced no transuranic waste and in fact, could consume transuranic waste. It proceeded as far as large-scale tests but was then canceled by the U.S. Government. Another approach, considered safer but requiring more development, is to dedicate subcritical reactors to the transmutation of the left-over transuranic elements.

There have also been theoretical studies involving the use of fusion reactors as so called "actinide burners" where a fusion reactor plasma such as in a tokamak, could be "doped" with a small amount of the "minor" transuranic atoms which would be transmuted to lighter elements upon their successive bombardment by the very high energy neutrons produced by the fusion of deuterium and tritium in the reactor. It was recently found by a study done at MIT, that only 2 or 3 fusion reactors with parameters similar to that of the International Thermonuclear Experimental Reactor (ITER) could transmute the entire annual actinide production from all of the light water reactors presently operating in the United States fleet while simultaneously generating approximately 1 gigawatt of power from each reactor.

Reuse of waste

Another option is to find applications of the isotopes in nuclear waste so as to reuse them. [12] . Already, cesium 137, strontium 90 and a few other isotopes are extracted for certain industrial applications such as food irradiation and RTGs.

Space disposal

Space disposal is an attractive notion because it permanently removes nuclear waste from the environment. However, it has significant disadvantages, not least of which is the potential for catastrophic failure of a launch vehicle. Furthermore, the high number of launches that would be required makes the proposal impractical. To further complicate matters, international agreements on the regulation of a such a program would need to be established.[13]

Accidents involving radioactive waste

A number of incidents have occurred when radioactive material was disposed of improperly, shielding during transport was defective, or when it was simply abandoned or even stolen from a waste store.^{[citation needed]} In the former Soviet Union, a nation having a high level of technical expertise and experience with nuclear issues, waste stored in a lake was accidentally blown all over the area during a dust storm after the lake had dried out.^{[citation needed]} One still must not stop ones car when driving through for any reason. In other cases lakes or ponds with radioactive waste accidentally overflowed into the rivers during exceptional storms.^{[citation needed]}

Scavenging of abandoned radioactive material has been the cause of several other cases of radiation exposure, mostly in developing nations, which usually have less regulation of dangerous substances (and sometimes less general education about radioactivity and its hazards) and a market for scavenged goods and scrap metal. The scavengers and those who buy the material are almost always unaware that the material is radioactive and it is selected for its aesthetics or scrap value.^{[citation needed]} A few are aware of the radioactivity, but are either ignorant of the risk or believe that the material's value outweighs the danger.^{[citation needed]} Irresponsibility on the part of the radioactive material's owners, usually a hospital, university or military, and the absence of regulation concerning radioactive waste, or a lack of enforcement of such regulations, have been significant factors in radiation exposures. For details of radioactive scrap see the Goiânia accident.

Transportation accidents involving spent nuclear fuel from power plants are unlikely to have serious consequences due to the strength of the spent nuclear fuel shipping casks.

See also

• Global Nuclear Energy Partnership
• Hot cell
• List of nuclear accidents
• Nuclear power
• Stored Waste Examination Pilot Plant
• Geomelting
• Radioactive scrap metal
• Yucca Mountain proposed nuclear-waste storage facility

References

1. ^ Krivtsov, A.I., 2006, Geoenvironmental Problems of Mineral Resources Development, in Geology and Ecosystems, Zekster (Ru), Marker (UK), Ridgeway (UK), Rogachevskaya (Ru), & Vartanyan (Ru), 2006 Springer Inc.,
2. ^ [ http://www.em.doe.gov/PDFs/170016EM_FYP_Final_3-6-06.pdf.]
3. ^ [ http://www.em.doe.gov/PDFs/170016EM_FYP_Final_3-6-06.pdf.]
4. ^ [ http://www.em.doe.gov/PDFs/170016EM_FYP_Final_3-6-06.pdf.]
5. ^ American Scientist Jan/Feb 2007
6. ^ [ http://www.em.doe.gov/PDFs/170016EM_FYP_Final_3-6-06.pdf.]
7. ^ [ http://www.em.doe.gov/PDFs/170016EM_FYP_Final_3-6-06.pdf.]
8. ^ [ http://www.em.doe.gov/PDFs/170016EM_FYP_Final_3-6-06.pdf.]
9. ^ [ http://www.em.doe.gov/PDFs/170016EM_FYP_Final_3-6-06.pdf.]
10. ^ Survey & Identification of NORM Contaminated Equipment
11. ^ Why WIPP?
12. ^ Removal of Silicon from High Level Waste Streams via Ferric Flocculation

Fentiman, Audeen W. and James H. Saling. Radioactive Waste Management. New York: Taylor & Francis, 2002. Second ed. An overview of waste from the nuclear fuel cycle was written by B.V. Babu and S. Karthik, Energy Education Science and Technology, 2005, 14, 93-102.

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