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Greek fire was a burning-liquid weapon used by the Byzantine Greeks, typically in naval battles to great effect as it could continue burning even on water. "Byzantine fire" was largely responsible for many Byzantine military victories, and partly the reason for the Byzantine Empire surviving as long as it did. The formula was a secret and remains a mystery to this day. As one contemporary victim of Greek fire advised his comrades, "every time they hurl the fire at us, we go down on our elbows and knees, and beseech Our Lord to save us from this danger."
OriginTheophanes records that Greek fire was invented c. 670 in Constantinople by Kallinikos (Callinicus), an architect from Heliopolis the Byzantine province of Syria.[1] Historian James Partington thinks it likely that "Greek fire was really invented by the chemists in Constantinople who had inherited the discoveries of the Alexandrian chemical school".[2] Many accounts note that the fires it caused could not be put out by pouring water on the flames—on the contrary, the water served to spread them, suggesting that 'Greek fire' was a flammable liquid that can float on water—it may have been a form of naphtha or another low-density liquid hydrocarbon as petroleum was known to eastern chemists long before its use became widespread in the 1800s. Use
However, it was used primarily at sea. It is rumored that the key to Greek fire's effectiveness was that it could continue burning under almost any conditions, even under water. It was known to the Byzantines' enemies as a "wet, dark, sticky fire" because it stuck to the unfortunate object it hit and was impossible to extinguish. Enemy ships were often afraid to come too near to the Byzantine fleet, because, once within range, the fire gave the Byzantines a strong military advantage. The last testimony of Greek Fire usage was in the fall of Constantinople in 1453, where the secret itself was destroyed in the flames of the Ottoman torches. Link to Byzantine victoriesByzantine fire was largely responsible for many Byzantine military victories, and partly the reason the Eastern Roman Empire survived as long as it did. It was particularly helpful near the end of the empire's life when there were not enough inhabitants to effectively defend its territories. It was first used to repel the Muslim Arab siege of Constantinople in 674-677 (Battle of Syllaeum), and in 717-718. The Byzantines also used this powerful weapon against the Rus in the Rus'-Byzantine War of 941 and against the Venetians during the Fourth Crusade. It quickly became one of the most fearsome weapons of the medieval world. The mere sight of any sort of siphon, whether it was used for Greek fire or not, was often enough to defeat an enemy. However, Greek fire was very hard to control, and it would often accidentally set Byzantine ships ablaze. Although similar substances have been invented in the modern age, the exact composition of the original Greek fire is unknown.
ManufactureThe ingredients, process of manufacture, and usage were a very carefully guarded military secret — so secretive that it remains a source of speculation to this day. Speculations include:
It is not clear if it was ignited by a flame as the mixture emerged from the syringe, or if it ignited spontaneously when it came into contact with water, or even air. If the former is the case, it is possible that the active ingredient was calcium phosphide, made by heating lime, bones, and charcoal. On contact with water, calcium phosphide releases phosphine, which ignites spontaneously. The reaction of quicklime with water also creates enough heat to ignite hydrocarbons, especially if an oxidizer such as saltpeter is present. However, Greek fire was also used on land. These ingredients were apparently heated in a cauldron, and then pumped out through a siphon or large syringe (known as a siphonarios) mounted on the bow of the ship. Such ship was herself called siphonophoros. It could also be used in hand grenades, made of earthenware vessels. If a pyrophoric reaction was involved, perhaps these grenades contained chambers for the fluids, which mixed and ignited when the vessel broke on impact with the target. TestimonyImage:Greek Fire Catapult (Harper's Engraving).png This possibly anachronistic lithograph from a 1869 Harper's Magazine depicts a 13th century engine for throwing Greek fire in a barrel. The Memoirs of Jean de Joinville, a thirteenth century French nobleman, include these observations of Greek fire during the Seventh Crusade:[1]
In the arts
See alsoNotes
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